| 1 Feb 1575 | Portuguese colony | Leaders |
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| 11 Jun 1951 | Portuguese overseas province | Leaders |
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| 11 Nov 1975 | independence (People's Republic of Angola) | Leaders |
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| 27 Aug 1992 | Republic of Angola | Leaders |
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| 1698 - 1701 | Luís César de Meneses | Governors |
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| 1701 - 1702 | Bernardino de Tavora de Sousa Tavares (b. 16... - d. 1702) | Governors |
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| 1705 - 1709 | Lourenço de Almada | Governors |
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| 1709 - 1713 | António de Saldanha de Albuquerque Castro e Ribafria | Governors |
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| 1713 - 1717 | João Manuel de Noronha | Governors |
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| 1717 - 1722 | Henrique de Figueiredo e Alarcão | Governors |
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| 1722 - 1725 | António de Albuquerque Coelho de Carvalho | Governors |
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| 1725 - 1726 | José Carvalho da Costa (acting) | Governors |
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| 1726 - 1732 | Paulo Caetano de Albuquerque | Governors |
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| 1732 - 1738 | Rodrigo César de Meneses | Governors |
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| 1738 - 1748 | Joaquim Jacques de Magalhães | Governors |
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| 1748 - 1749 | Fonseca Coutinho (acting) | Governors |
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| 1749 - 1753 | António de Almeida Soares e Portugal, conde do Lavradio (b. 1699 - d. 1761) | Governors |
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| 1753 - 1758 | António Alvares da Cunha | Governors |
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| 1758 - 1764 | António de Vasconcelos | Governors |
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| 1764 - 1772 | Francisco Inocéncio de Sousa Coutinho | Governors |
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| 1772 - 1779 | António de Lencastre | Governors |
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| 1779 - 1782 | José Gonçalo da Gama | Governors |
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| 1784 - 1790 | José de Almeida e Vasconcelos, barão de Moçâmedes (b. 1737 - d. 18...) | Governors |
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| 1790 - 1797 | Manuel de Almeida e Vasconcelos, visconde da Lapa | Governors |
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| 1797 - 1802 | Miguel António de Melo | Governors |
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| 1802 - 1806 | Fernão António de Noronha | Governors |
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| 1807 - 1810 | António de Saldanha da Gama | Governors |
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| 1810 - 1815 | José de Oliveira Barbosa | Governors |
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| 1816 - 1819 | Luís da Motta Fêo e Torres | Governors |
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| 1819 - 1821 | Manoel Vieira Tovar de Albuquerque | Governors |
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| 1821 - 1822 | Joaquim Inácio de Lima | Governors |
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| 1822 - 1823 | Junta | Governors |
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| 1823 | Cristóvão Avelino Dias | Governors |
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| 1823 - 1829 | Nicolau de Abreu Castelo-Branco | Governors |
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| 1829 - 1834 | José Maria de Sousa Macedo Almeida e Vasconcelos, barão de Santa Comba Dão (b. 1787 - d. 1872) | Governors |
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| 1834 - 1836 | Junta | Governors |
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| 1836 | Domingos de Saldanha Oliveira e Daun (b. 1800 - d. 1836) | Governors |
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| 1837 - 1839 | Bernardo Vidal | Governors-general |
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| 1839 | António Manuel de Noronha | Governors-general |
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| 1839 - 1842 | Manuel Eleutério Malheiro (acting) | Governors-general |
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| 1842 - 1843 | José Xavier Bressane Leite | Governors-general |
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| 1843 - 1845 | Lourenço Germack Possolo | Governors-general |
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| 1845 - 1848 | Pedro Alexandrino da Cunha | Governors-general |
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| 1848 - 1851 | Adrião de Silveiro Pinto | Governors-general |
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| 1851 - 1853 | António Sérgio de Sousa | Governors-general |
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| 1853 | António Ricardo Graça | Governors-general |
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| 1853 - 1854 | Miguel Ximenes Rodrigues Sandoval de Castro e Viegas, visconde de Pinheiro (b. 1806 - d. 1884) | Governors-general |
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| 1854 - 1860 | José Rodrigues Coelho do Amaral | Governors-general |
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| 1860 - 1861 | Carlos Augusto Franco | Governors-general |
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| 1861 - 1862 | Sebastião Lopes de Calheiros e Meneses (b. 1816 - d. 1899) | Governors-general |
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| 1862 - 1865 | José Baptista de Andrade | Governors-general |
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| 1865 - 1868 | Francisco António Gonçalves Cardoso (b. 1800 - d. 1875) | Governors-general |
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| 1868 - 1870 | José Rodrigues Coelho do Amaral | Governors-general |
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| 1870 - 1873 | José Maria da Ponte e Horta | Governors-general |
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| 1873 - 1876 | José Baptista de Andrade | Governors-general |
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| 1876 - 1878 | Caetano Alexandre de Almeida e Albuquerque (b. 1824 - d. 1916) | Governors-general |
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| 1878 - 1880 | Vasco Guedes de Carvalho e Meneses | Governors-general |
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| 1880 - 1882 | António Eleutério Dantas | Governors-general |
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| 1882 - 1886 | Francisco Joaquim Ferreira do Amaral (b. 1844 - d. 1923) | Governors-general |
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| 1886 - 1892 | Gilherme Auguste de Brito Capelo | Governors-general |
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| 25 Aug 1892 - Sep 1893 | Jaime Lôbo de Brito Godins (acting) | Governors-general |
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| 1893 - 1896 | Álvaro Ferreira | Governors-general |
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| 1896 - 1897 | Gilherme Auguste de Brito Capelo | Governors-general |
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| 1897 - 1900 | António Duarte Ramada Curto | Governors-general |
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| 1900 - 1903 | Francisco Xavier Cabral de Oliveira Moncada | Governors-general |
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| 1903 - 1904 | Eduardo Augusto Ferreira da Costa | Governors-general |
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| 1904 | Custódio Miguel de Borja | Governors-general |
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| 1904 - 1905 | António Duarte Ramada Curto | Governors-general |
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| 1905 - 1906 | Caminho de Ferro de Mossámedes | Governors-general |
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| 1906 - 1907 | Eduardo Augusto Ferreira da Costa | Governors-general |
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| Jun 1907 - Jun 1909 | Henrique Mitchell de Paiva Couceiro (b. 1861 - d. 1944) | Governors-general |
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| 1909 | Álvaro António da Costa Ferreira | Governors-general |
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| 1909 - 1910 | José Augusto Alves Roçadas | Governors-general |
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| 1910 - 1911 | Caetano Francisco Cláudio Eugénio Gonçalves (acting) | Governors-general |
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| 1911 - 1912 | Manuel Maria Coelho | Governors-general |
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| 1912 - 1915 | José Mendes Ribeiro Norton de Matos (b. 1867 - d. 1955) | Governors-general |
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| 1915 - 1916 | António Júlio da Costa Pereira de Eça | Governors-general |
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| 1916 - 1917 | Pedro Francisco Massano de Amorim | Governors-general |
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| 1917 - 1918 | Jaime Alberto de Castro Morais | Governors-general |
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| 1918 - 1919 | Filomeno da Câmara Melo Cabral | Governors-general |
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| 1919 - 1920 | Mimoso Guera (acting) | Governors-general |
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| 1920 - 1921 | Francisco Coelho do Amaral Reis, visconde de Pedralva (b. 1873 - d. 1938) | Governors-general |
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| 1921 - 1924 | José Mendes Ribeiro Norton de Matos (s.a.) | High commissioners and governors-general |
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| 1924 | João Augusto Crispiniano Soares | High commissioners and governors-general |
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| 1924 - 1926 | Francisco Cunha Rêgo Cháves | High commissioners and governors-general |
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| 1926 - 1928 | António Vicente Ferreira | High commissioners and governors-general |
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| 1928 - 1929 | António Damas Mora (acting) | High commissioners and governors-general |
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| 1929 - 1931 | Filomeno da Câmara | High commissioners and governors-general |
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| 1931 - 1933 | José Dionisio Carneiro de Sousa e Faro | High commissioners and governors-general |
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| 1933 - 1935 | Eduardo Ferreira Viana | High commissioners and governors-general |
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| 1936 - 1940 | António Lopes Matheus | High commissioners and governors-general |
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| 1940 - 1942 | Manoel da Cunha e Costa Marques Mano | High commissioners and governors-general |
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| 1942 - 1943 | Álvaro de Freitas Morna | High commissioners and governors-general |
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| 1943 - 1947 | Vasco Lopes Alves | High commissioners and governors-general |
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| 1948 - 1955 | José Agapito de Silva Carvalho | High commissioners and governors-general |
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| 1955 - 1956 | Manoel de Gusmão Mascarenhas Gaivão (b. 1901) | High commissioners and governors-general |
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| 1957 - Jan 1960 | Horacio José de Sá Viana Rebelo | High commissioners and governors-general |
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| 15 Jan 1960 - Jun 1961 | Álvaro Rodrigues da Silva Tavares | High commissioners and governors-general |
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| 23 Jun 1961 - 26 Sep 1962 | Venâncio Augusto Deslandes | High commissioners and governors-general |
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| Sep 1962 - 1966 | Silvino Silvério Marques | High commissioners and governors-general |
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| 27 Oct 1966 - 1972 | Camilo Augusto de Miranda Rebocho Vaz (b. 1920) | High commissioners and governors-general |
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| Oct 1972 - May 1974 | Fernando Augusto Santos e Castro | High commissioners and governors-general |
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| May 1974 - 15 Jun 1974 | Joaquín Franco Pinheiro (acting) | High commissioners and governors-general |
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| 15 Jun 1974 - 24 Jul 1974 | Silvino Silvério Marques | High commissioners and governors-general |
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| 24 Jul 1974 - 28 Jan 1975 | António Alva Rosa Coutinho | High commissioners and governors-general |
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| 28 Jan 1975 - 2 Aug 1975 | António Silva Cardoso | High commissioners and governors-general |
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| 2 Aug 1975 - 26 Aug 1975 | Ernesto Ferreira de Macedo | High commissioners and governors-general |
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| 26 Aug 1975 - 10 Nov 1975 | Leonel Cardoso | High commissioners and governors-general |
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| 11 Nov 1975 - 10 Sep 1979 | Agostinho Neto | Presidents |
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| 10 Sep 1979 - | José Eduardo dos Santos | Presidents |
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| 11 Nov 1975 - 9 Dec 1978 | Lopo do Nascimento | Prime ministers |
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| 19 Jul 1991 - 2 Dec 1992 | Fernando José de França Dias Van-Dúnem (1st time) (b. 1952) | Prime ministers |
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| 2 Dec 1992 - 3 Jun 1996 | Marcolino Moco | Prime ministers |
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| 3 Jun 1996 - 29 Jan 1999 | Fernando José de França Dias Van-Dúnem (2nd time) (s.a.) | Prime ministers |
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| 6 Dec 2002 - | Fernando da Piedade Dias dos Santos (b. 1952) | Prime ministers |
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