| 12 Feb 1818 | independence declared (State of Chile) | Leaders |
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| 9 Jul 1826 | Republic of Chile | Leaders |
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| 12 Feb 1818 - 28 Jan 1823 | Bernardo O'Higgins | Supreme Directors |
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| 28 Jan 1823 - 29 Mar 1823 | Agustín de Eyzaguirre | Supreme Directors |
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| 29 Mar 1823 - 5 Apr 1823 | Congress of Plenipotentiaries - Juan Egaña (b. 1769 - d. 1836) - Manuel Fernando Vásquez de Novoa (b. 1783 - d. 18...) - Manuel Antonio González | Supreme Directors |
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| 5 Apr 1823 - 13 Aug 1823 | Ramón Freire (1st time) | Supreme Directors |
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| 13 Aug 1823 - 2 Sep 1823 | Deputy Supreme Junta - Mariano Egaña (b. 1793 - d. 1846) - Santiago Fernández (b. 1768 - d. 1847) - Diego José Benavente (b. 1790 - d. 1867) | Supreme Directors |
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| 2 Sep 1823 - 9 Jul 1826 | Ramón Freire (2nd time) | Supreme Directors |
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| 9 Jul 1826 - 9 Sep 1826 | Manuel Blanco Encalada | Presidents |
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| 9 Sep 1826 - 1 Feb 1827 | Agustín de Eyzaguirre | Presidents |
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| 1 Feb 1827 - 8 May 1827 | Ramón Freire (1st time) 15 Feb 1827) | Presidents |
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| 8 May 1827 - 16 Jul 1829 | Francisco Antonio Pinto (1st time) | Presidents |
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| 16 Jul 1829 - 19 Oct 1829 | Francisco Ramón de Vicuña | Presidents |
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| 19 Oct 1829 - 2 Nov 1829 | Francisco Antonio Pinto (2nd time) | Presidents |
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| 2 Nov 1829 - 7 Nov 1829 | Francisco Ramón de Vicuña | Presidents |
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| 7 Nov 1829 - 13 Nov 1829 | Ramón Freire (2nd time) | Presidents |
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| 13 Nov 1829 - 7 Dec 1829 | Francisco Ramón de Vicuña | Presidents |
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| 7 Dec 1829 - 24 Dec 1829 | Ramón Freire (3rd time) | Presidents |
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| 24 Dec 1829 - 18 Feb 1830 | José Tomás Ovalle (1st time) | Presidents |
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| 18 Feb 1830 - 1 Apr 1830 | Francisco Antonio Ruiz Tagle | Presidents |
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| 1 Apr 1830 - 21 Mar 1831 | José Tomás Ovalle (2nd time) | Presidents |
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| 21 Mar 1831 - 18 Sep 1831 | Fernando de Errázuriz | Presidents |
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| 18 Sep 1831 - 18 Sep 1841 | Joaquín Prieto | Presidents |
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| 18 Sep 1841 - 18 Sep 1851 | Manuel Bulnes | Presidents |
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| 18 Sep 1851 - 18 Sep 1861 | Manuel Montt | Presidents |
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| 18 Sep 1861 - 18 Sep 1871 | José Joaquín Pérez | Presidents |
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| 18 Sep 1871 - 18 Sep 1876 | Federico Errázuriz Zañartu | Presidents |
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| 18 Sep 1876 - 18 Sep 1881 | Aníbal Pinto | Presidents |
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| 18 Sep 1881 - 18 Sep 1886 | Domingo Santa María | Presidents |
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| 18 Sep 1886 - 29 Aug 1891 | José Manuel Balmaceda | Presidents |
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| 29 Aug 1891 - 31 Aug 1891 | Manuel Baquedano | Presidents |
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| 31 Aug 1891 - 18 Sep 1896 | Jorge Montt 10 Nov 1891; Head of the Executive to 26 Dec 1891) | Presidents |
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| 18 Sep 1896 - 12 Jul 1901 | Federico Errázuriz Echaurren | Presidents |
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| 12 Jul 1901 - 18 Sep 1901 | Aníbal Zañartu Zañartu (acting) | Presidents |
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| 18 Sep 1901 - 18 Sep 1906 | Germán Riesco | Presidents |
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| 18 Sep 1906 - 16 Aug 1910 | Pedro Montt | Presidents |
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| 16 Aug 1910 - 6 Sep 1910 | Elías Fernández Albano (acting) | Presidents |
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| 6 Sep 1910 - 23 Dec 1910 | Emiliano Figueroa Larraín | Presidents |
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| 23 Dec 1910 - 23 Dec 1915 | Ramón Barros Luco | Presidents |
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| 23 Dec 1915 - 23 Dec 1920 | Juan Luis Sanfuentes | Presidents |
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| 23 Dec 1920 - 12 Sep 1924 | Arturo Alessandri Palma | Presidents |
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| 12 Sep 1924 - 23 Jan 1925 | Luis Altamirano Talavera | Presidents |
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| 23 Jan 1925 - 27 Jan 1925 | Pedro Pablo Dartnell Encina | Presidents |
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| 27 Jan 1925 - 1 Oct 1925 | Arturo Alessandri Palma | Presidents |
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| 1 Oct 1925 - 23 Dec 1925 | Luis Barros Borgoño (acting) | Presidents |
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| 23 Dec 1925 - 10 May 1927 | Emiliano Figueroa Larraín | Presidents |
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| 10 May 1927 - 29 Jul 1931 | Carlos Ibáñez del Campo | Presidents |
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| 29 Jul 1931 - 4 Jun 1932 | Juan Esteban Montero Rodríguez | Presidents |
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| 4 Jun 1932 - 16 Jun 1932 | Arturo Puga Osorio | Presidents |
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| 16 Jun 1932 - 13 Sep 1932 | Carlos Dávila Espinoza 8 Jul 1932, then Provisional President of the Socialist Republic of Chile) | Presidents |
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| 13 Sep 1932 - 2 Oct 1932 | Bartolomé Blanche Espejo | Presidents |
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| 2 Oct 1932 - 24 Dec 1932 | Abraham Oyanedel Urrutia (acting) | Presidents |
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| 24 Dec 1932 - 24 Dec 1938 | Arturo Alessandri Palma | Presidents |
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| 24 Dec 1938 - 25 Nov 1941 | Pedro Aguirre Cerda | Presidents |
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| 25 Nov 1941 - 2 Apr 1942 | Jerónimo Méndez Arancibia | Presidents |
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| 2 Apr 1942 - 27 Jun 1946 | Juan Antonio Ríos Morales | Presidents |
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| 27 Jun 1946 - 17 Oct 1946 | Alfredo Duhalde Vásquez (acting) | Presidents |
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| 3 Aug 1946 - 17 Oct 1946 | Vicente Merino Bielich | Presidents |
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| 17 Oct 1946 - 3 Nov 1946 | Juan Antonio Iribarren Cabezas | Presidents |
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| 3 Nov 1946 - 3 Nov 1952 | Gabriel González Videla | Presidents |
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| 3 Nov 1952 - 3 Nov 1958 | Carlos Ibáñez del Campo | Presidents |
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| 3 Nov 1958 - 3 Nov 1964 | Jorge Alessandri Rodríguez | Presidents |
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| 3 Nov 1964 - 3 Nov 1970 | Eduardo Frei Montalva | Presidents |
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| 3 Nov 1970 - 11 Sep 1973 | Salvador Allende | Presidents |
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| 11 Sep 1973 - 27 Jun 1974 | Junta - Augusto Pinochet Ugarte (b. 1915 - d. 2006) - José Toribio Merino Castro (b. 1915 - d. 1996) - Gustavo Leigh Guzmán (b. 1920 - d. 1999) - César Mendoza Durán (b. 1918 - d. 1996) | Presidents |
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| 27 Jun 1974 - 11 Mar 1990 | Augusto Pinochet Ugarte | Presidents |
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| 11 Mar 1990 - 11 Mar 1994 | Patricio Aylwin Azócar | Presidents |
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| 11 Mar 1994 - 11 Mar 2000 | Eduardo Frei Ruiz-Tagle | Presidents |
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| 11 Mar 2000 - 11 Mar 2006 | Ricardo Lagos Escobar | Presidents |
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| 11 Mar 2006 - | Michelle Bachelet (f) | Presidents |
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